| 1 | Topps Logo | Contents | - |
| 2 | UCL Trophy | Contents | - |
| 3 | 2022/23 Official UCL Matchballs | Contents | - |
| 4 | Thibaut Courtois (Real Madrid C.F.) | 2021/22 UCL Team of the Season | shiny |
| 5 | Trent Alexander-Arnold (Liverpool FC) | 2021/22 UCL Team of the Season | shiny |
| 6 | Antonio Rüdiger (Chelsea FC) | 2021/22 UCL Team of the Season | shiny |
| 7 | Virgil van Dijk (Liverpool FC) | 2021/22 UCL Team of the Season | shiny |
| 8 | Andrew Robertson (Liverpool FC) | 2021/22 UCL Team of the Season | shiny |
| 9 | Kevin De Bruyne (Manchester City FC) | 2021/22 UCL Team of the Season | shiny |
| 10 | Fabinho (Liverpool FC) | 2021/22 UCL Team of the Season | shiny |
| 11 | Luka Modrić (Real Madrid C.F.) | 2021/22 UCL Team of the Season | shiny |
| 12 | Kylian Mbappé (Paris Saint-Germain) | 2021/22 UCL Team of the Season | shiny |
| 13 | Karim Benzema (Real Madrid C.F.) | 2021/22 UCL Team of the Season | shiny |
| 14 | Vinícius Jr. (Real Madrid C.F.) | 2021/22 UCL Team of the Season | shiny |
| 15 | Karim Benzema (Player of the Season) | 2021/22 UCL Team of the Season | shiny |
| 16 | Pauline Peyraud-Magnin (Juventus) | 2021/22 UWCL Standout Performers | shiny |
| 17 | Lisa Boattin (Juventus) | 2021/22 UWCL Standout Performers | shiny |
| 18 | Saki Kumagai (FC Bayern München) | 2021/22 UWCL Standout Performers | shiny |
| 19 | Mapi León (FC Barcelona) | 2021/22 UWCL Standout Performers | shiny |
| 20 | Ashley Lawrence (Paris Saint-Germain) | 2021/22 UWCL Standout Performers | shiny |
| 21 | Aitana Bonmatí (FC Barcelona) | 2021/22 UWCL Standout Performers | shiny |
| 22 | Patri Guijarro (FC Barcelona) | 2021/22 UWCL Standout Performers | shiny |
| 23 | Lena Oberdorf (VfL Wolfsburg) | 2021/22 UWCL Standout Performers | shiny |
| 24 | Alexia Putellas (FC Barcelona) | 2021/22 UWCL Standout Performers | shiny |
| 25 | Tabea Waßmuth (VfL Wolfsburg) | 2021/22 UWCL Standout Performers | shiny |
| 26 | Marie-Antoinette Katoto (Paris Saint-Germain) | 2021/22 UWCL Standout Performers | shiny |
| 27 | Mike Maignan | AC Milan | figured |
| 28 | Davide Calabria (Captain) | AC Milan | foil, figured |
| 29 | Fikayo Tomori | AC Milan | figured |
| 30 | Fodé Ballo-Touré | AC Milan | figured |
| 31 | Theo Hernández | AC Milan | figured |
| 32 | Simon Kjær | AC Milan | figured |
| 33 | Pierre Kalulu | AC Milan | figured |
| 34 | Rade Krunić | AC Milan | figured |
| 35 | Ismaël Bennacer | AC Milan | figured |
| 36 | Sandro Tonali | AC Milan | figured |
| 37 | Alexis Saelemaekers | AC Milan | figured |
| 38 | Brahim Díaz | AC Milan | figured |
| 39 | Rafael Leão | AC Milan | figured |
| 40 | Olivier Giroud (Golden Goalscorer) | AC Milan | foil, figured |
| 41 | Ante Rebić | AC Milan | figured |
| 42 | Divock Origi | AC Milan | figured |
| 43 | Tommaso Pobega (Next Gen) | AC Milan | - |
| 44 | Brahim Díaz / Rafael Leão (Double Impact) | AC Milan | foil |
| 45 | Remko Pasveer | AFC Ajax | figured |
| 46 | Daley Blind | AFC Ajax | figured |
| 47 | Calvin Bassey | AFC Ajax | figured |
| 48 | Jurriën Timber | AFC Ajax | figured |
| 49 | Owen Wijndal | AFC Ajax | figured |
| 50 | Perr Schuurs | AFC Ajax | figured |
